Investigation of structural phase transitions in minerals and analogue systems by high-temperature magic-angle-spinning nuclear magnetic resonance spectroscopy
Posted on:1991-03-11
Degree:Ph.D
Type:Dissertation
University:University of Illinois at Urbana-Champaign
Candidate:Phillips, Brian L
Full Text:PDF
GTID:1470390017952388
Subject:Mineralogy
Abstract/Summary:
This work comprises studies of structural phase transitions (SPT's) in three different phases (anorthite CaAl;Insight regarding structural changes for all three phases was obtained from the temperature dependence of the chemical shift. In Chapter 1 the temperature variation of the modulation wave in the incommensurate phase of Sr;For anorthite and AlPO...