The Fullerene Ramifications: Synthesis And Assembly With Nanoparticles

The studies on the synthesis and properties of fullerene derivatives had been an active topic in the fullerene chemistry. So synthesis novel fullerene derivatives and their assembly with functional nanoparticles, searching reaction rules, studying their photophysical and photochemical properties and exploring fullerene-base new materials are remarkably meaningful. This will play an important role in developing the fullerene chemistry. This thesis is focused on the synthesis and properties of novel fullerene derivatives and their assembly with functional nanoparticles.1. Two kinds of C60 derivations containing thiol group were synthesized by 1,3-dipolar cycloaddition reaction, which were characterized by 1H-NMR, UV and IR spectroscopy. The self-assembly of Ag, Au nanoparticles with the C60 derivatives and their photophysical properties were first studied.2. The hybrid materials based on the self-assembly of C60 derivatives with CdS, CdSe nanoparticles were first fabricated, which were characterized by 1H-NMR and UV-Vis spectroscopy.3. Two kinds of simple fullerene pyrrolidines were synthesized by 1,3-dipolar cycloaddition reaction, which were characterized by 1H-NMR, UV and IR spectroscopy. Chlorination of the fullerene pyrrolidines by ICl are first studied, the products were characterized by 1H-NMR, UV, IR spectroscopy and fluorescence spectrum.4. A new compound containing multi-ester was synthesized and was characterized by 1H-NMR spectroscopy, it is a precursor for a new C60 derivative with excellent solubility and optical limiting property.