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Preparation And Application Of Ferrocene Derivatives Self-assmbled Modified Electrode

Posted on:2007-06-21Degree:MasterType:Thesis
Country:ChinaCandidate:X H DengFull Text:PDF
GTID:2121360185992852Subject:Analytical Chemistry
Abstract/Summary:PDF Full Text Request
For more than 50 years ferrocene derivatives have attracted a continuous and increasing interest in many areas of chemistry because of their unique optical, thermal and redox behaviour. Among their properties the most important perhaps are their redox ones. Its redox characteristics are sensitive to both covalent and noncovalent binding to other molecules. Due to this fact several ferrocene derivatives incorporated in molecular and supramolecular structures have been used as electron transfer catalysts and molecular sensors.This thesis around how the adoption forms couples the legal system to have stable ferrocene modified electrode and its applications to launch under the condition of gentle by passing to design and control from a grope of tail regiment that assemble the list member, the born and homologous chemistry key assemble the ferrocene to the electrode up and polished the electrode electrochemistry property to carry on the research to the ferrocene study, acquired to give or get an electric shock the live material with from the information of a self assembled member interaction. It not only enlarge the method of ferrocene assembled electrode, decrease largely the diffculity of preparation, but also extended ferrocene to polish the application of the electrode, raised the selectivity and intelligent degrees of some materials examination obviously.Fristly, Based on the redox character of ferrocene, we studied the electrochemistry character of ferrocene and its derivatives with glass carbon electrode. The influence of both resonance and inductive effects on the electrochemistry character of ferrocene were investigated by cyclic...
Keywords/Search Tags:Ferrocene, Self-assembled, Modified electrode, Epinephrine, Hydroquinone, Colloid Au, Terbutaline
PDF Full Text Request
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