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Synthesis And Characterization Of Magnetic Polymer Microspheres With Surface Functional Groups

Posted on:2008-10-26Degree:MasterType:Thesis
Country:ChinaCandidate:X Y ZhangFull Text:PDF
GTID:2121360215993190Subject:Polymer Chemistry and Physics
Abstract/Summary:PDF Full Text Request
The Fe3O4 nanoparticles have been prepared by the chemical precipitationmethod. The Fe3O4 nanoparticles are about 10 nm diameter with an average. Wewill modify it by dispersion polymerization. The organic modified magnetitenanoparticles were synthesized by the coprecipitation and surfacemodification with HEMA Characterized by TEM, the ultrafme Fe3O4/P(St-HEMA)nanospheres had well dispersion and stabilization in aqueous fluids.The superparamagnetic Fe3O4/P(St-HEMA) nanospheres with an average diameterof 1μm were characterized significantly with functional hydroxy groups.Next, The Fe3O4 nanoparticles were modified by graft polymerication withMPS and emulsion polymerication. The graft polymerication magneticnanoparticles by the Surface modification with MPS and MMA. Characterizedby TEM,IR,TG,DSC and AFM. The ultrafme Fe3O4/(MPS-PMMA) nanospheres hadwell dispersion and stabilization.In aqueous fluids, The superparamagntic Fe3O4/(MPS-PMMA) nanosphereswith an average diameter of 20-30nm were characterized significantly withfunctional groups.Compared with dispersion polymerization, the graft polymerication magneticnanoparticles have more dispersion and more stabilization and its diametermore smaller. Thus, it is can be used in many fields, such as biotechnologyand other fields. Finally, the nanofibre with modified oleic acid wereprepared by inversemulision Polymerization. All the polymerizationnanospheres have superparamagnitic.
Keywords/Search Tags:Fe3O4 nanospheres, superparamagnitism, dispersion, graft polymerication, inverseemulision polymerization
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