Preparation And Characterization Of Some New Acrylate Monomers And Research Of Their Polymerization

Several new monomers were synthesized and polymerization conditions were studied at different initiators.The process of the preparation consists of:1,Trans-β-N, N diethyl amino methacrylate was synthesized via the methyl propargyl (MP) and diethylamine. The effects of temperature, reactant ratio and catalyst (Ph3P) were investigated,and a free radical,anionic polymerization, as well as MMA, St of polymerization were studied.The results show that,The yield of trans-β-N, N diethyl amino methacrylate could reach 70; a preliminary polymerization study found that:Trans-β-N, N diethyl amino methacrylate can hardly be polymerized;2,Free radical and anionic polymerization of the trans-β-methoxy methacrylate (purchase) were studied.The results show that,the polymerization is difficult;3,αand trans-β-methoxy-acrylic acid methyl ester was synthesized via the methyl propargyl (MP),Ph3P and methanol.The effects of reactant ratio was investigated,and a free radical, anionic polymerization, as well as MMA, St of polymerization were studied.The results show that,αand trans-β-methoxy-acrylic acid methyl ester 80% with proportion about 1:1.α-methoxy-acrylic acid methyl ester can only be radical copolymerized with styrene producing copolymer with more styrene units;4,1,1-diphenyl ethylene (DPE) was synthesized by organic synthesis and its structural characterization and purity were analyzed,97.7% purity. A polymerization of DPE and St was studied.