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A Facile Transformation Of N-arylpyrroles Into Partially Fluorinated Pyrroloquinoline Derivatives

Posted on:2015-09-29Degree:MasterType:Thesis
Country:ChinaCandidate:W H LiangFull Text:PDF
GTID:2181330431996387Subject:Organic Chemistry
Abstract/Summary:PDF Full Text Request
Reaction of N-arylpyrroles with n-BuLi followed by the addition of hexafluoro-benzene provided partially fluorinated pyrroloquinoline derivatives(3a~3m), andtheir UV-vis absorption, emission and electrochemical properties were investigated.To our knowledge, the novel compounds3a~3m, containing pyrrole and indole ring,were first synthesized and emmit strong bule fluorescence in both solution and thesolid state. Besides, stacking fashion of product3b and3f are very interesting.
Keywords/Search Tags:1-phenyl-1H-pyrrole, pyrroloquinoline, organic fluorine molecules, polycyclic aromatic hydrocarbons (PAHs), photoelectric material
PDF Full Text Request
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