Ferrocene Amine Derivatives And The Synthesis And Electrochemical Properties Of Ferrocene Acid Complexes

In this thesis, two novel amino ferrocene derivatives 7a and 7b were synthesized and characterized by elemental analysis, IR and ~1H NMR spectra. The electrochemical properties of compounds were studied farther. In addition, two single crystals of the complexes containing 1.1'-ferrocenedicarboxylic were gained and the electrochemical properties of compounds were also studied.Part 11. Synthesis of the compoundsTwo novel compounds 7a and 7b of ferrocene derivatives were synthesized. The structure of the compounds was determined by element analysis, IR and ~1H NMR spectrum.The synthesis of compounds was set out in Scheme1-1 2. Electrochemical properties of the compoundsIn order to study the properties of the compounds deeply, six ferroenyl schiff bases derivatives 9(a~c) and 10(a~c) were also synthesized and studied by electrochemical properties and quantum calculation.The electrochemical properties of twe series of the compounds were investigated by many electrochemical methods and determined kinetic parameters. The results indicated that: the reaction on the electrode were controlled by diffusion; the redox properties of ferrocene are not changed after connected with benzene, but it would be influenced by the different substitutions on the phenyl ring; the different substitutions on the phenyl ring is not obviously influence the diffusivities of the electrode reaction, but it has visible infection to constant of electrode action.3. Quantum calculation of the compoundsThe quantum calculation of these compounds were determined and described. We studied the components and proportions of molecular orbital energy and mulligan charges.Part 21. Two complexes containing 1.T-ferrocenedicarboxylic A and B were synthesized,2. All the complexes were characterized by elemental analysis and IR spectra. The electrochemical properties of the complexes were studied too.3. Two single crystals of the complexes containing 1.1 '-ferrocenedicarboxylic were obtained, the X-ray single crystal structure analysis indicated that: the complex A is a polmer with two-dimensional constructure and the B is a binuclear cores complex.