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Palladacycle-Catalyzed Cross-Coupling Reactions Of Arylboronic Acids With Carboxylic Anhydride Or Acyl Chloride

Posted on:2013-07-16Degree:MasterType:Thesis
Country:ChinaCandidate:L ShenFull Text:PDF
GTID:2231330371976474Subject:Organic Chemistry
Abstract/Summary:PDF Full Text Request
In this thesis, the triphenylphosphine-cyclopalladated ferrocenylimine (Cat.2) exhibited highly catalytic activity for the both of arylboronic acids with carboxylic anhydride and acyl chloride with low catalyst loading (0.5mol%). Up to98%yield was obtained for25examples. It is noting that catalyst2can be reused for eight times without losing its catalytic activity. Scheme1...
Keywords/Search Tags:Palladacycle, Arylboronic acids, Carboxylic anhydride, Acyl chloride
PDF Full Text Request
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