| Multi-nitrogen heterocyclic coordination polymer as a widely used chelating ligands hasbeen a research focus of chemists for their Nonlinear Optical Properties、Preferably electrontransport properties and Physical and chemical properties. With the continuous developmentof the research, it becomes very easy to get. Metal-organic frameworks, also known ascoordination polymers, are a type of self-assembly formed by organic ligands and metal ions.They are a new type of material, which have an extensive application prospect. Metal-organiccomplex has attracted much more attention for their fascinating structural diversity andspecific functionality, which have made them highly promising in various applications,particularly absorption, catalysis and molecular magnetization.In this paper, fourteen complexes have been hydrothermally synthesized throughhydrothermal technology with carboxylate ligands and transition metal ions. And thesecomplexes are characterized by X-ray, IR spectrum, element analysis, thermo gravimetryanalysis and fluorescent spectroscopy.[Mn（L）（HL）（Cl）]（1）、[Cd2（L）2（1,4-chdc）2（H2O）2]·H2O（2）、[Mn（1,4-ndc）（L）]（3）、[Pb2（L）（1,4-ndc）2]·0.5H2O（4）、[Cd2（L）2（H2adp）2]（5）、[Cd2（L）2（1,4-ndc）2]·H2O（6）、[Cd（L）（1,4-ndc）]·0.5H2O（7）、[Cd2（L）2（1,3,5-BTC）（Cl）]·H2O（8）、[Pb（L）（1,4-ndc）]·0.5H2O（9）、[Pb（L）（1,3-bdc）]·2.5H2O（10）、[Pb2（L）2（1,4-bdc）2]n（11）、[Mn3（cis-chdc）2（trans-chdc）（L）2]（12）、[Cu2（L）2（1,4-BDC）（Cl）2]（13）、[Co2（L）2（1,2,4,5-BTC）（H2O）2]（14）。... |
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