Metal/TBHP-catalyzed Alkene Difunctionalization Reactions: The Synthesis Of1,4-dicarbonyl Compounds And β-hydroxy Ketones

In recent years, alkene difunctionalization reactions have been attractingwidespread attention from organic chemists. Because which rapidly increases molecularcomplexity. This thesis mainly studies alkene difunctionalization reactions in thepromotion of the transition metals and peroxides.This thesis composes with two major parts as follows:Firstly, Co-Catalyzed Synthesis of1,4-Dicarbonyl Compounds Using TBHPOxidant.We reported a new method of furnishing1,4-Dicarbonyl Compounds using alkenesand-bromo carbonyl compounds under the effect of Co(acac)2and TBHP. operation ofthe reaction is simple and can be directly carried out in the air.Secondly, the Transition Metals-Catalyzed Synthesis of β-Hydroxy Ketones UsingTBHP Oxidant.We found a new method of generatig β-hydroxy ketones using alkenesand isopropanol under the effect of transition metals and TBHP. This way completelydifferent from traditional approaches. Unfortunately the yield is low now. Somethingabout this work is on progress in our laboratory.