Synthesis And Properties Of 1,3,5-based Triphenylbenzene Three Pyridine Ligands And Metal-organic Complexes

The design and synthesis of novel functional nanosized space complexes have been one of the most interesting research topics in metal-organic chemistry and crystal engineering. They have been used extensively for highly specific molecular recognition and reactions. Such nanospaces were widely exploited for a variety of purposes. This paper have synthesised two N-dope polycyclic aromatic hydrocarbons compounds by suzuki coupling reaction. In this dissertation, one transition-metal Ag molecule cage compound base on N-dope PAHs are designed and constructed successfully. This organic caged compound is characterized by NMR, ESI, X-ray single crystal diffraction, X-ray powder diffraction, IR spectra and luminescence analyses. This dissertation includes the following three parts:Chapter1:Introduction,the concepts and principles of PAH, the application of Suzuki coupling reaction are summarized.Chapter2:Two polycyclic nitrogen-containing compound were synthesized and charactered by NMR, ESI, X-ray single crystal diffraction.Chapter3:organic caged compound with the polycyclic nitrogen-containing ligand have been synthesized successfully and charactered by NMR, ESI, X-ray single crystal diffraction,X-ray powder diffraction, IR spectra and luminescence analyses.In conclusion, summarize the full text, and look forward to future work.