With the development of the supramolecular chemistry,more and more people have paid attention to synthesizing the supramolecular polymers which have some functions instead of exploring the structure of them.There are a variety of nitrogen heterocyclic cations which can conduct the structures of a series of Cu???/Ag???halide/pseudohalide supramolecular polymers which have novel structure and special optical,electric,magnetic,semiconductive and photocatalytic performance.In this thesis,a series of divalent cations as template agents were synthesized and reacted with Cu???/Ag???halide/pseudohalide via slow evaporation approach at room temperature.Finally,nine novel supramolecular polymers were obtained.In addition,we explored the structures and the properties of compounds 1-9 by a variety of techniques.Firstly,we regarded 1,4-bis[?3,5-lutidine?-N-methylene]benzene dibromide and 1,4-bis[?4-picoline?-N-methylene]benzene dibromide as template agents to reacting with Cu???/Ag???halide/pseudohalide and compounds 1-6 were obtained.They were {?BLMB?0.5[Cu?SCN?2]}n?1?,{?BPMB?0.5[Cu?SCN?2]}n?2?,{?BPMB?[CuBr3]}n?3?,{?BPMB?[HgI4?H2O?0.66]}n?4?,{?BPMB?[Cu2I4]}n?5?and {?BPMB?2[Ag4I8]}n?6?.We analyzed the structures of compounds 1-6 by X-ray single-crystal diffraction,infrared spectroscopy?IR?and elemental analysis and characterized the properties of compounds 1-6 by fluorescence spectrum and ultraviolet-visible?UV-vis?absorption spectrum.The results indicated that compound 1 has a 2D polypseudorotaxane structure;Compound 2 displays a 1D chain structure.Compounds 3 and 4 are the mononuclear structures;Compounds 5 and 6 have the multinuclear cubane structures.Compounds 1-6 showed good photocatalytic abilities for methylene blue?MB?irradiated by visible light.The effective detection of Fe3+ was performed by compounds 1-6 as fluorescent sensors.Then we employed bivalent cations 1,2-bis?4-aminopyridine?ethane dibromide,1,3-bis?4-aminopyridine?propanedibromide and 1,4-bis?4-aminopyridine?butane dibromide as template agents to reacting with Cu???/Ag???halide/pseudohalide and compounds 7-9 were obtained.They were {?BAPE?0.5[Cu?SCN?2]}n?7?,{?BAPP?[Cu2?SCN?4]}n?8?and {?BAPB?0.5[Cu?SCN?2]}n?9?.The results showed that compounds 7 and 9 have 2D polypseudorotaxane structures.Compound 8 is a 3D network structure.Compounds 7-9 showed good photocatalytic abilities for methylene blue?MB?and rhodamine B?RhB?irradiated by visible light. |