| In this paper,five new nitrogen-containing ligands were selected namely:11-fluoro-dipyrido[3,2-a:2?,3?-c]phenazine?L1?,2-?2-chloro-6-fluorophenyl?-1H-imidazo[4,5-f][1,10]phenanthroline?L2?,Pyridine[3,2-a:2?,3?-c:3??,2??-h:2???,3???-j]phenazine?tetrapyrido-[3,2-a:2?,3?-c:3??,2??-h:2???,3???-j]phenazine??tpphz?,2-?4-fluorophenyl?-1H-imidazo[4,5-f][1,10]?L3?and 2-?3-dipyrido?-1H-imidazo[4,5-f][1,10]phenanthroline?PIP?as main ligands and use different acids:1,4-H2chdc,H2L4,H2nica and H2L5 as auxiliary ligands and use Cd?II?/Ni?II?/Pb?II?/Cu?II?/Mn?II?as metal ions,synthesis of five coordination polymers by hydrothermal method which have been determined by the X-ray single crystal diffraction analysis,elemental analysis,X-ray powder diffraction patterns,magnetic susceptibility,IR spectra,thermal analyses,fluorescence spectroscopy characters and properties.[Cd3?L1?2?cis-1,4-chdc?2?trans-1,4-chdc?]?1?[Ni?L2??SO4??H2O?2]n?2?[Pb2?L4??tpphz?1.5?NO3?2]·H2O?3?[Cu2?L3??nica?Cl]2?4?[Mn?L5??PIP?]2·H2O?5?... |
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