| In this paper,five new nitrogen-containing ligands were selected namely:11-fluoro-dipyrido[3,2-a:2?,3?-c]phenazine（L1）,2-（2-chloro-6-fluorophenyl）-1H-imidazo[4,5-f][1,10]phenanthroline（L2）,Pyridine[3,2-a:2′,3′-c:3′′,2′′-h:2′′′,3′′′-j]phenazine（tetrapyrido-[3,2-a:2′,3′-c:3′′,2′′-h:2′′′,3′′′-j]phenazine）（tpphz）,2-（4-fluorophenyl）-1H-imidazo[4,5-f][1,10]（L3）and 2-（3-dipyrido）-1H-imidazo[4,5-f][1,10]phenanthroline（PIP）as main ligands and use different acids:1,4-H2chdc,H2L4,H2nica and H2L5 as auxiliary ligands and use Cd（II）/Ni（II）/Pb（II）/Cu（II）/Mn（II）as metal ions,synthesis of five coordination polymers by hydrothermal method which have been determined by the X-ray single crystal diffraction analysis,elemental analysis,X-ray powder diffraction patterns,magnetic susceptibility,IR spectra,thermal analyses,fluorescence spectroscopy characters and properties.[Cd3（L1）2（cis-1,4-chdc）2（trans-1,4-chdc）]（1）[Ni（L2）（SO4）（H2O）2]n（2）[Pb2（L4）（tpphz）1.5（NO3）2]·H2O（3）[Cu2（L3）（nica）Cl]2（4）[Mn（L5）（PIP）]2·H2O（5）... |
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