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Studies of the Use of Electrochemical Impedance Spectroscopy to Characterize and Assess the Performance of Lacquers Used to Protect Aluminum Sheet and Can Ends

Posted on:2014-08-07Degree:M.A.ScType:Thesis
University:Carleton University (Canada)Candidate:Ali, MohammadFull Text:PDF
GTID:2451390008453573Subject:Engineering
Abstract/Summary:
This study involved investigating the feasibility of using Electrochemical Impedance Spectroscopy to assess the performance of coatings used to protect aluminum in beverage containers, and developing an accelerated testing procedure. In the preliminary investigation, tests were performed to ensure that the EIS systems at hand are capable, functional and consistent. This was followed by EIS testing of kitchen-aluminum foil and high-impedance epoxy polymer as a baseline for chemically-active and chemically-inert systems. The ability of EIS to differentiate between intact and flawed coatings was tested by investigating deliberately damaged coatings. The effects of varying the pH and oxygen content on the performance of the coated aluminum samples were also tested. From this investigation, it has been concluded that EIS can be used to differentiate between intact and flawed coatings and detect corrosion before it is visually observable. Signatures of corrosion have been recorded and a preliminary testing procedure has been drawn.
Keywords/Search Tags:Performance, Used, Aluminum, Coatings, EIS
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