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Nickel Based Catalyst for Hydrocracking of Light Aromatics and Middle Distillates to Light Paraffins

Posted on:2013-11-21Degree:M.EngType:Thesis
University:University of Calgary (Canada)Candidate:Hernandez, EumirFull Text:PDF
GTID:2451390008469079Subject:Engineering
Abstract/Summary:
The content of aromatics in the gasoline must be reduced due to environmental regulations; which means that there will be a surplus of these compounds in the refineries. A solution to this surplus is to convert them into light paraffins used as feedstock for the petrochemical industry.;In this study, three novel bifunctional catalysts consisting of nickel supported on a ZSM-5 zeolite where tested and compared using toluene as a model molecule. Based on their products yield one catalyst was selected to be tested with hydrotreated light cycle oil.;This work includes all the details concerning catalyst testing, feedstock analyses and a kinetic study for Ni-ZSM-5 catalysts prepared by different methods. As a whole this thesis shows the feasibility of replacing the Pd-ZSM-5 with the Ni-ZSM-5 for aromatics ring opening. A particular route of interest was the incorporation of Ni during the preparation at the early step of zeolite synthesis.
Keywords/Search Tags:Aromatics, Light, Catalyst
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