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Boronate macrocycle formation using boron-Lewis base dative bonds and boronic acid-diol condensation reactions

Posted on:2014-05-11Degree:M.SType:Thesis
University:Western Carolina UniversityCandidate:Rizzo, Natalie RoseFull Text:PDF
GTID:2451390008959772Subject:Chemistry
Abstract/Summary:
Synthesis of boronate ester compounds via condensation reactions using either an amine or an amine N-oxide coupled with a boronic acid. Synthesis of boronate ester compounds using quinoline isomers coupled with 2, 3-dihydroxynaphthalene was also attempted. These compounds form B-N dative bonds, and potentially form macrocycles capable of trapping a guest molecule in the cavity. The exact sizes of the complexes are unknown at this time. Characterization of these compounds was performed by 1H NMR, FT-IR, mass spectroscopy, and 13C NMR.
Keywords/Search Tags:Boronate, Using, Compounds
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