Studies on the thermal decomposition of organic polysulphanes

Posted on:1992-12-25

Degree:M.Sc

Type:Thesis

University:University of Calgary (Canada)

Candidate:Oriakhi, Christopher O

Full Text:PDF

GTID:2471390017450131

Subject:Organic Chemistry

Abstract/Summary:

The thermal decomposition of dimethyl and bis(methylphenyl) polysulphanes (CH;Dimethyl polysulphane (DMPS) exhibited different decomposition behaviour in open and closed systems. Analysis using HPLC, GC-MS, and ;The addition of hydrogen sulphide was found to inhibit the decomposition of DMPS in the closed system whereas extensive decomposition was observed without H;Bis(methylphenyl) polysulphane exhibited remarkable stability over dimethyl polysulphane and did not show evidence of decomposition at 150...

Keywords/Search Tags:

Decomposition, Polysulphane, Dimethyl

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