The chemistry of binuclear iron complexes possessing bridging organic ligands |
Posted on:1990-02-02 | Degree:Ph.D | Type:Thesis |
University:The Pennsylvania State University | Candidate:Mirkin, Chad Alexander | Full Text:PDF |
GTID:2471390017454628 | Subject:Inorganic Chemistry |
Abstract/Summary: | |
he studies described in this thesis have focused upon the chemistry of binuclear iron complexes with bridging organic ligands and their relevance to synthetic organic chemistry.;The ;Under photochemical conditions complex 3 will reinsert CO to form complex 2. Under thermal conditions complex 3 reacts with CO to form 2-ferra-4-pyrrolin-2-one complex Fe;Complex 3 and its derivatives photochemically insert alkynes between the iron-carbon bond of their metallacyclic rings to form 2-ferra-pyridine complexes Fe;The cationic ;The... |
Keywords/Search Tags: | Complex, Bridging organic ligands, Chemistry |
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