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The chemistry of binuclear iron complexes possessing bridging organic ligands

Posted on:1990-02-02Degree:Ph.DType:Thesis
University:The Pennsylvania State UniversityCandidate:Mirkin, Chad AlexanderFull Text:PDF
GTID:2471390017454628Subject:Inorganic Chemistry
Abstract/Summary:
he studies described in this thesis have focused upon the chemistry of binuclear iron complexes with bridging organic ligands and their relevance to synthetic organic chemistry.;The ;Under photochemical conditions complex 3 will reinsert CO to form complex 2. Under thermal conditions complex 3 reacts with CO to form 2-ferra-4-pyrrolin-2-one complex Fe;Complex 3 and its derivatives photochemically insert alkynes between the iron-carbon bond of their metallacyclic rings to form 2-ferra-pyridine complexes Fe;The cationic ;The...
Keywords/Search Tags:Complex, Bridging organic ligands, Chemistry
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