The Catchment of Daling River locates in the northwest of LiaoNing province, water resources very needy. In recent years, along with economy of northwest development, the ecosystem environment of river valley is very bad, the water is polluted seriously. The text selected 10 representational points and appraised part of them which attained in 1983, 1993, 1998, 2003 using single evaluation of single-item set, synthesized evaluation, fuzzy adjudication, related clustering, related distance analyze and gray associated analyze. After statistical analysised the whole ChaoYang city underground water quality data which collected in 1993, 1998, 2003 and social and economic indicator, we forecast the underground water quality of ChaoYang of 2008, 2013 and 2018 using gray system theory model by using graphical method, bring forward the biggest discharge of sewage and advised sewage, and advanced the countermeasure and idea and environment development stratagem on the base of actuality of source of pollution of the drainage area.
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