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Lithographic performance and application of i-line and DUV photoresists for advanced integrated circuit technology. Thulium dioctyl terephthalate(5-) as an extracellular space marker and NMR shift reagent for quantitative determination of tissue. The ch

Posted on:1997-08-16Degree:D.ChemType:Dissertation
University:The University of Texas at DallasCandidate:Makos, Janice DFull Text:PDF
GTID:1461390014980105Subject:Chemistry
Abstract/Summary:
In an effort to futher increase throughput and performance, high speed, positive tone i-line and DUV photoresists were evaluated and compared by depth of focus (DoF), resist profile, linearity, and contrast. Based on the data presented in this report, Resist A should have a higher resolution and a wider process latitude than Resist B. Throughput increased by 88% when a high speed photoresist and the Canon FPA3000 iW Wide Field stepper were used. In order to produce integrated circuits with sub-0.25 {dollar}mu{dollar}m features, chemically amplified photoresists were compared and evaluated. The resists were capable of producing 0.25 {dollar}mu{dollar}m WS and isolated lines, as well as, 0.30 {dollar}mu{dollar}m contact holes. Continued process optimization will improve resist performance for specific applications.; Practicum two. The fundamental practicum report on "TmDOTP{dollar}sp{lcub}5-{rcub}{dollar} as an Extracellular Space Marker and NMR Shift Reagent for Quantitative Determination of Tissue Intracellular Sodium" determined the relative extracellular space (rECS) was the same for both TmDOTP{dollar}sp{lcub}5-{rcub}{dollar} and CoEDTA{dollar}sp{lcub}-{rcub}{dollar} in the in vivo heart and liver, showing that both agents experience the same ECS. TmDOTP{dollar}sp{lcub}5-{rcub}{dollar}, as an in vivo {dollar}sp{lcub}23{rcub}{dollar}Na NMR shift reagent, was used to quantify {dollar}rmlbrack Nasp{lcub}+{rcub}rbracksb{lcub}i{rcub}{dollar} in in vivo livers both by NMR and AAS. The results compared favorably with previous results obtained from AAS techniques.; Practicum one. The investigation "The Chemistry of Cr(VI) in a Constructed Wetland" determined the effectiveness of a laboratory scale wetland in removing toxic Cr(VI) from a 100 ppm Cr(VI) waste stream for one year. The results of batch studies suggested the primary removal method was through complexation of chromium with the carboxylate groups in organic matter.
Keywords/Search Tags:NMR shift reagent, Resist, Extracellular space, Performance
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