A thermodynamic analysis of tubular SOFC based hybrid systems

The goals of this research are to develop analysis strategy for Solid Oxide Fuel Cell (SOFC) based systems, to apply the analysis strategy to tubular SOFC hybrid systems and to identify promising hybrid configurations.; Existing SOFC models do not fully integrate the heat and mass transfer with the electrochemistry while existing system models do not include simulation capabilities for required power cycle equipment (e.g., SOFC). In addition, currently proposed hybrid systems are not optimized for system thermal efficiency or are too complex; factors contributing to increased cost of electricity through increased initial and/or operating and maintenance costs. Analytical models are developed for the tubular SOFC and other hybrid system components such that hybrid cycles may be configured and analyzed.; A pressurized tubular SOFC combined with an intercooled-reheat gas turbine (SureCell™ cycle) is chosen as the Base Cycle over which improvements are sought. The humid air turbine (HAT) cycle features are incorporated to the Base Cycle resulting in the SOFC-HAT hybrid cycle which shows an efficiency of 69.05% while the Base Cycle has an efficiency of 66.23%.; Exergy analysis identified the superior efficiency performance of the SOFC component. Therefore, an additional cycle variation added a second SOFC component followed by a low pressure combustor in place of the reheat combustor of the gas turbine of the SOFC-HAT hybrid. The resulting Dual SOFC-HAT hybrid has a thermal efficiency of 75.98%.; The Single SOFC-HAT hybrid gives the lowest cost of electricity (3.54¢/kW-hr) while the Dual SOFC-HAT hybrid has the highest cost of electricity (4.02¢/kW-hr) among the three cycles with natural gas priced at {dollar}3/GJ. The Dual SOFC-HAT hybrid plant cost is calculated to be significantly higher because the fraction of power produced by the SOFC(s) is significantly higher than that in the other cases on the basis of {dollar}1100/kw initial cost for the SOFC. The Dual SOFC-HAT hybrid can only be justified in favor of the Single SOFC-HAT hybrid when price of natural gas is greater than {dollar}14/GJ or if a severe carbon tax on the order of {dollar}180/ton of CO2 is imposed while natural gas is priced at {dollar}3/GJ.