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Synthesis And Propertiies Of Mental-Organic Framework

Posted on:2009-02-07Degree:MasterType:Thesis
Country:ChinaCandidate:W D XuFull Text:PDF
GTID:2121360242477153Subject:Analytical Chemistry
Abstract/Summary:PDF Full Text Request
Metal-Organic Framework is a forefront and top field in science. This work introduced 11 new kinds of Mantal-Organic Frameworks obtained by new organic ligands and metal ion synthesis and the self–assembly method. The major work was forcused on three aspects as follows:1. 6 new organic ligands were designed and synthesized.2. 11 kinds of Mental-Organic Famworks were obtained by self-asembly of the new ligands mentioned above. [Cu2(L1)2·2DMF]n [Cu2(L2)2·2DMF]n [Co(L3)4(ClO4)2·2DMF]n Zn2(L4)2(N3)4 [Mn2(L4)-4(H2O)4(CH-3OH)2(SO4)2]n [Cd(L4)2(NO3)2 ]-n [Co2(L5)2(bdc)2(H2O)2·(H2O)2]n [Ni2(L5)2(bdc)2(H2O)2·(H2O)2]n [Co(L5)2(N3)2]n [Cu(L5)2(NO3)2·H2O]n [Zn3(BDC)4(H2O)4]n3. The structures and properties were characterized by single crystal X-ray diffaction, IR, photoluminescence.
Keywords/Search Tags:Mental-Organic Framework, Organic Ligands, Self-assembly, Supramolecular Chemistry
PDF Full Text Request
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