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Additives On Zinc Electrodeposition Process

Posted on:2007-06-08Degree:MasterType:Thesis
Country:ChinaCandidate:Y J LiFull Text:PDF
GTID:2191360185953765Subject:Non-ferrous metallurgy
Abstract/Summary:PDF Full Text Request
Zinc is one of the important nonferrous metals, which occupies an momentous status in the national economy. The electrolytic deposit of is the last process step in hydrometallurgy of zinc, which is extract zinc from solution in water with H2SO4. The energy consumption in electrolytic deposit process is very massiveness, it has great effect to capitalized cost in hydrometallurgy of zinc. Adding some additives is one of the efficient approach to get zinc with good quality, Which has great significance to solve some factory practice such as enhancement quality of zinc , economy cost and increase current efficiency. It is a important condition to combination additives and make it optimum. It is necessary to us to choose proper additives, researching in depth additives' reaction mechanism is indispensability.This experiment nvestigation thirteen additives simulation process parameter in industrial, then control optimization them. This text testing over ten reagents such as glutin, DBS. and thiourea, which had an influence up on surface quality of zinc as additives. Optimize some additives which is good effect to we have more thorough research in mechanism of action through photo. The experiments reveal that single additive have different effect to cathode zinc, cresol can improve surface quality in zinc ,get high current efficiency , restrain re dissolve in zinc deposition, thiourea is a good additive it has action preventing oxygenation. Glutin is absolutely necessarily in deposition process of zinc, compare single additive, compounded additive can make more ideal effect. Ideal additive can enhancement surface quality of zinc. increase current efficiency, economy cost obviously , additive can also depression return- dissolution phenomenon, has some value in industry.
Keywords/Search Tags:Hydrometallurgy of zinc, Electrowinning, Additives, Deposition, Surface quality
PDF Full Text Request
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