Synthesis And Property Of Metal Phosphate Metal Containing Nitrogen Heterocyclic Compound

A series of metal phosphites have been synthesized. Two single crystal structures of chloro(triphenyl phosphite) copper(I) complex and cyano(triphenyl phosphite) copper(I) complex have been obtained by X-ray single diffraction analysis and these two complexes have also been characterized by EA,IR,UV and TG/DTG. Additionally, the electrochemical properties of chloro(triphenylphosphito) copper(I) complex and cyano(triphenyl phosphite) copper(I) complex were performed by cyclic voltammetric approach. Further more, cyano(triphenyl phosphite) copper(I) shows well absorption in fluorescence spectra analyse.Three organic phosphate acids— methylene(phenyl)phosphonous acid,methyl hydrogen P-toylphosphonate acid and 4-chlorophosphonic acid,have been designed and synthesized Then a series of metal phosphates of the three phosphate acid have been systhesized.A new ligand phenyl-thiocarbamic acid O-pyridin-4-ylmethyl ester which may have biological activities has been designed and synthesized ,and then a series of metal phenyl-thiocarbamic acid O-pyridin-4-ylmethyl ester complexes have also been obtained.The structure of phenyl-thiocarbamic acid O-pyridin-4-ylmethyl ester has been obtained by X-ray single diffraction analysis and these complexes have also been...