In this thesis,we reported FeCl3 catalyzed hydroamination of alkenes and the synthesis of zirconium and nickel compounds.The reaction mechanisms of the hydroamination reactions were also explored.They are expressed in details as follows:In the first part,the reaction mechanisms of the hydroamination reactions and its characteristic were summarized,so as to express the intention and significance of this research.In the second part,FeCl3-catalyzed hydroamination of alkene was reported.The yield of the reaction was calculated.The reaction mechanism was also explored.In the third part,zirconium and nickel complexes were synthesized and characterized by NMR and X-ray crystal diffraction.
|