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Study On Preparation And Properties Of Nano-Titanium Fluorocarbon Anticorrosion Coating

Posted on:2011-08-02Degree:MasterType:Thesis
Country:ChinaCandidate:P Y ZhaoFull Text:PDF
GTID:2131330338980199Subject:Inorganic Chemistry
Abstract/Summary:PDF Full Text Request
As the fluorocarbon resin has excellent weather resistance, heat resistance, stability, and hydrophobic, oleophobic properties, it is currently one of the focuses in coating industry. Adding nano-scale in the paint can greatly enhance the coating corrosion resistance. This combination of the double advantages of fluorocarbon resin and nano-scales help developing a high corrosion resistance of coatings, then property testing was carried out, and the mechanism of the anti-corrosion coating and curing kinetics was explored.By doing a lot of experiments the optimum formula for the anti-corrosion coating was determined: PTFE particle size of 0.5 10μm; binder resin P-200 chosen as the end group-OH, molecular weight of medium B-03 type; mixed solvent composition including N, N-dimethylformamide (10%), N-methyl pyrrolidone (25%), toluene (20%), cyclohexanone (35%), methyl ethyl ketone (5%), acetone (5%) ; PTFE dosage of 8g/100g P-200; titanium nano-scale dosage of 8g/100g P-200.Coating process is divided into low-temperature drying and high temperature sintering in two stages. By DSC experiments and kinetic calculations, optimization process are: drying temperature 25℃100℃, drying time 2030min; sintering temperature 300℃ 340℃, sintering time 20 25min.Adhesion, flexibility level of such coating can achieve Grade 1, impact resistance 80kg, hardness 5H. At 80℃under high temperature accelerated corrosion, anti-corrosion time in ASP solution reached over 600h. In 30% sulfuric acid solution, 30% sodium hydroxide solution, 10% hydrochloric acid, corrosion over time reached 450h; the corrosion current reached the order of 10-8. These data show excellent corrosion resistance.
Keywords/Search Tags:fluorocarbon resin, anticorrisive coatings, PTFE, P-200 resin
PDF Full Text Request
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