Orientation Construction And Structure Characterization Of Metal Coordination Compounds Directed By N-containing Organic Cations

Under certain conditions, coordination polymers with high regulation can be synthesized by metal ions and organic cations through molecular assembly and crystal engineering method. Coordination polymers are the research hotspot at present, this project has used eight novel cations as organic structural direction reagents carriers on the molecular assemble, and eight novel organic/inorganic compounds were synthesized. The influence of organic cations and inorganic metal ions to the structures and properties of coordination complexes was studied in this paper. They exhibit some unique properties and exist potential application values in nonlinear optical materials, superconducting materials, magnetic substances and catalyses.Also their crystal structures were determined by X-ray single crystal diffractometer technology. In these 8 complexes, the compounds 1,2,3,4,5 formed the one-dimensional chain structures; the compounds 6,7,8 are the single nuclear supramolecular structures.Finally, the IR spectrums and the fluorescence spectrums have been characterized, and the spectrum characters of this kind of complexes were initially reported.