The composition of synthetic detergent wastewater which was produced by Xi'an Nanfeng Daily Chemical Plant, is very complicated, and the content of organic matter is high. The wastewater contains a lot of linear alkyl benzene sulfonate (LAS), which is hard to be biodegradable, and the color is tan, partial alkaline, multi-bubble. It has a certain toxicity, and has a greater impact for the the water environment. Furthermore, it also has a strong foaming and emulsifying properties, so the treatment is very diffcult. As for the properties of LAS, investigations had been performed on biodegradability of synthetic detergent firstly , and emphases had been put on experimental analysis on Anaerobic Biofilter . During the proess of hydrolytie acidifieation, big molecules had been divided into small molecules , and unbiogradable substances were also converted into biodegradable substances in the wastewater , so as to lay the foundation for the aerobic biological treatment of the follow-up. On this basis, deside to adopt the two-stage membrane model of AF anaerobic biological filter - aerobic biological contact oxidation Joint Process to treat wastewater.The two-stage membrane experiment showed that AF operated in the conditions of HRT=24h and temperature 32±2℃, the macromolecules organic pollutants had been degraded effectively ,and the removal rate of LAS and COD can be up to 50% and 30% respectively. The ration of BOD/COD had been increased from 0.3 to 0.5 around, and the biodegradability of wastewater improved greatly. Aerobic biofilter operated in the conditions of LAS<40mg/L, HRT=12h and DO=4-5mg/L, the final effluent of comprehensive biochemical treatment is COD<40mg/L and LAS<5mg/L, reaching I-class criteria specified in Integrated Wastewater Discharge Standard(GB 8978-1996). In practice, the basic national policy of protecting the ecology and the environment, which as the strategy of sustainable development had been executed well.The two-stage membrane joint technology provided a reasonable and reliable technology programmes and technical operating parameters for industrial application, and deduced the matrix degradation dynamic model of aerobic biological contact oxidation treatment LAS: 0.72( 0.3288) K S=37.69mg/L, and the coefficient R2=0.9879。...
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