Assembly, Structures And Properties Of Metal-Organic Frameworks Based On3-Carboxymethoxy Phenyl Acrylic Acid

Due to unique catalytic activity, optical properties, magnetic properties and biological properties, metal-aromatic carboxylicate complexes have got the wide attention of people. They plays an important role in magnetic materials, nonlinear optical materials and microporous material.This thesis selects3-carboxymethoxy phenyl acrylic acid as the ligand to build supramolecular complexes, We have hydrothermally synthesized fifteen metal-organic complexes with3-carboxymethoxy phenyl acrylic acid: First of all, these complexes’structures were preliminary characterized by single-crystal X-ray diffraction.Then some specific complexes were further characterized by elementary analysis, IR, thermo-gravimetric andfluorescence spectra. It was also investigated how to control the assembly of coordination polymers with desired properties, moreover, the relation between structure and property was discussed.