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[Pd(allyl)Cl]2 Catalyzed Amination Of Aryl Chlorides In Presence Of N-Heterocyclic Carbene

Posted on:2010-01-07Degree:MasterType:Thesis
Country:ChinaCandidate:Z P ZhangFull Text:PDF
GTID:2231360278958114Subject:Biochemical Engineering
Abstract/Summary:PDF Full Text Request
In the chapter one, first, we reviewed the Pd combined with P ligands catalyzed C-N coupling reactions. Many P ligands were applied in C-N coupling reactions and obtained good effect as studied of chemists; Second, we reviewed the developed of N-heterocyclic carbenes (NHCs), each complexs of metals and NHCs were synthesised and were applied in lots of reactions. So we confirm our research goal, seeking a better Pd catalyst to realize the amination of aryl chlorides in Presence of special NHC.In the chapter two, we discussed the amination of aryl chlorides catalyzed by [Pd(allyl)Cl]2 and SIPr.HCl. We get good results.
Keywords/Search Tags:Buchwald-Hartwing reaction, N-heterocyclic carbene, palladium, amination, aryl chlorides
PDF Full Text Request
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