In the chapter one, first, we reviewed the Pd combined with P ligands catalyzed C-N coupling reactions. Many P ligands were applied in C-N coupling reactions and obtained good effect as studied of chemists; Second, we reviewed the developed of N-heterocyclic carbenes (NHCs), each complexs of metals and NHCs were synthesised and were applied in lots of reactions. So we confirm our research goal, seeking a better Pd catalyst to realize the amination of aryl chlorides in Presence of special NHC.In the chapter two, we discussed the amination of aryl chlorides catalyzed by [Pd(allyl)Cl]2 and SIPr.HCl. We get good results. |